| Peer-Reviewed

Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid

Received: 7 June 2017     Accepted: 21 June 2017     Published: 24 July 2017
Views:       Downloads:
Abstract

Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.

Published in International Journal of Materials Science and Applications (Volume 6, Issue 4)
DOI 10.11648/j.ijmsa.20170604.18
Page(s) 212-222
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Fluoride Removal, Adsorption, Orange Juice Residue, Sulfuric Acid Treatment, Zr(IV) Loading

References
[1] Jha SK, Nayak AK, Sharma YK. (2009). Fluoride toxicity effect in onion (Allium cepal.) grown in contaminated soils. Chemosphere, 76: 353-356.
[2] Versessinina Y, Trapido M, Ahelik V, Munter R. (2001). Fluoride in drinking water: The problem and its possible solution. Proc. Estonian Acad. Sci. Chem., 50: 81-88, 2001.
[3] Huang CJ, Liu JC.(1999). Precipitate floatation of fluoride containing wastewater from semiconductor manufacturer. Water Res., 33: 3403-3412.
[4] Turner BD, Binning P, Stipp SLS. (2005) Fluoride removal by calcite: Evidence for fluoride precipitation and surface adsorption. Env. Sci. Technol., 39: 9561-9568.
[5] Samatya S, Mizuki H, Ito Y, Kawakita H, Uezu K. (2010). The effect of polystyrene as a progen on the fluoride ion sorption of Zr4+-surface immobilized resin. React. Funct. Polym., 70: 63-68.
[6] Wajima T, Umeta Y, Narita S, Sugawara K. (2009). Adsorption behavior of fluoride ion using a titanium hydroxide derived adsorbent. Desalination, 249: 323-330.
[7] Xu X, Burgess JO. (2003). Compressive strength, fluoride release and recharge of fluoride-releasing materials. Biomaterials, 24: 2451-2461.
[8] Fan X, Parker DJ, Smith MD. (2003). Adsorption kinetics of fluoride on low cost materials. Water Res., 37: 4929-4937, 2003.
[9] Meenakshi, Maheshwari RC. (2006). Fluoride in drinking water and its removal. J. Hazard. Mater., B137: 456-463
[10] Durmaz F, Kara H, Cengeloglu Y, Ersoz M. (2005). Fluoride removal by Donnan dialysis with anion exchange membranes. Desalination, 177: 51-57.
[11] Wioeniewski J, Rozanska A. (2007). Donnan dialysis for hardness removal from water before electodialytic desalination. Desalination, 212: 251-260.
[12] Zhang G, Gao Y, Zhang Y, Gu P. (2005). Removal of fluoride from drinking water by membrane coagulation reactor. Desalination, 177: 143-155.
[13] Volesky B. (1990). Biosorption of Heavy Metals. CRC Press, Boca Raton, USA.
[14] Marques PA, Pinherro HM, Teixeria JA, Rosa MF. (1999). Removal efficiency of Cu2+, Cd2+ and Pb2+ by waste brewery biomass: pH and cation association effects. Desalination, 124: 137-144.
[15] Ifuku Y. (1997). Production of juice from citrus fruits, In: Japan Fruit Juice Association (eds.): Novel Encyclopedia of Fruit Juices (in Japanese), Asakura Shoten Co.Ltd., Tokyo, Japan, pp. 81-113
[16] Kawakita H, Abe M, Inoue J, Ohto K, Harada H, Inoue K. (2009). Selective gold recovery using orange waste. Sep. Sci. Technol., 44: 2797-2805.
[17] Dhakal RP, Ghimire KN, Inoue K. (2005). Adsorptive separation of heavy metals from an aquatic environment using orange waste. Hydrometallurgy, 79: 182-190.
[18] Paudyal H, Pangeni B, Inoue K, Kawakita H, Ohto K, Harada H, Alam S. (2011). Adsorptive removal of fluoride from aqueous solution using orange waste loaded with multi-valent metal ions. J. Hazard. Mater., 192: 676-682.
[19] Paudyal H, Pangeni B, Inoue K, Matsueda M, Suzuki R, Kawakita H, Ohto K, Biswas BK, Alam S. (2012). Adsorptive behavior of fluoride ion on Zr(IV) loaded orange waste gel from aqueous solution, Sep. Sci. Technol., 47: 96-103.
[20] Paudyal H, Pangeni B, Inoue K, Kawakita H, Ohto K, Ghimire KN, Harada H, Alam S. (2013). Adsorptive removal of trace concentration of fluoride ion from water by using dried orange juice residue, Chem. Eng. J., 223: 844-853.
[21] Liao XP, Shi B. (2005). Adsorption of fluoride on zirconium(IV)-impregnated collagen fiber, Environ. Sci. Technol., 39: 4628-4632.
[22] Paudyal H, Pangeni B, Inoue K, Kawakita H, Ohto K, Ghimire KN, Alam S. (2013). Preparation of novel alginate based anion exchanger from Ulva japonica and its application for the removal of trace concentration of fluoride from water, Biores. Technol., 148, 221-227.
[23] Viswanathan N, Sundaram CS, Meenakshi S. (2009).: Sorption behavior of fluoride on carboxylated cross-linked chitosan beads, Coll. Surf. B; Bioint., 68, 48-54.
[24] Fang L, Ghimire KN, Kuriyama M, Inoue K, Makino K. (2003). Removal of fluoride using some lanthanum loaded adsorbents with different functional groups and polymer matrices, J. Chem. Technol. Biotechnol., 78: 1038-1047.
[25] Gupta VK, Ali I, Saini VK. (2007). Defluoridation of wastewaters using waste carbon slurry, Wat. Res., 41, 3307-3316: 2007.
[26] Mohan VS, Ramanaiah SV, Rajkumar B, Sharma PN. (2007). Bio-sorption of fluoride from aqueous solution onto algal spirogyra IO1 and evaluation of adsorption kinetics, Biores. Technol., 98: 1006-1011.
[27] Gao S, Cui J, Wei Z. (2009). Study on the fluoride adsorption of various apatite materials in aqueous solution, J. Fluo. Chem., 130: 1035-1041.
[28] Zhao Y, Li X, Liu L, Chen F. (2008). Fluoride removal by Fe(III)-loaded ligand exchange cotton cellulose adsorbent from drinking water, Carbohydr. Polym., 72: 144-150.
[29] Viswanathan N, Meenakshi S. (2010). Enriched fluoride sorption using alumina/chitosan composite, J. Hazard. Mater., 178: 226-232.
[30] Daifullah AAM, Yakout SM, Elreefy SA. (2007). Adsorption of fluoride in aqueous solution using KMnO4 modified activated carbon derived from steam pyrolysis of rice straw, J. Hazard. Mater., 147: 633-643.
[31] Sathish RS, Sairam S, Raja VG, Rao GN, Janardhana C. (2008). Defluoridation of water using zirconium impregnated coconut fiber carbon, Sep. Sci. Technol., 43: 3676-3694.
[32] Paudyal H, Pangeni B, Inoue K, Kawakita H, Ohto K, Alam S. (2012). Removal of fluoride from aqueous solution by using porous resin containing hydrated oxide of cerium (IV) or zirconium (IV). J. Chem. Eng. Japan, 45: 331-336.
[33] Kemer B, Ozdes D, Gundogdu A, Bulut VN, Duran C, Soylak M: Removal of fluoride ions from aqueous solution by waste mud, J. Hazard. Mater., 168, 888-894, 2009.
[34] Tor A. (2006). Removal of fluoride from an aqueous solution by using montmorillonite, Desalination, 201, 267-276.
[35] Sundaran CS, Viswanathan N, Meenakshi S. (2008). Uptake of F by nanohydroxyapatite/chitosan:- a bioinorganic composite, Biores. Technol., 99, 8226-8230.
[36] Islam M, Patel RK. (2007). Evaluation of removal efficiency of fluoride from aqueous solution using quick lime, J. Hazard. Mater., 143, 303-310.
Cite This Article
  • APA Style

    Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, et al. (2017). Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. International Journal of Materials Science and Applications, 6(4), 212-222. https://doi.org/10.11648/j.ijmsa.20170604.18

    Copy | Download

    ACS Style

    Hari Paudyal; Bimala Pangeni; Katsutoshi Inoue; Hiroyuki Harada; Hidetaka Kawakita, et al. Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. Int. J. Mater. Sci. Appl. 2017, 6(4), 212-222. doi: 10.11648/j.ijmsa.20170604.18

    Copy | Download

    AMA Style

    Hari Paudyal, Bimala Pangeni, Katsutoshi Inoue, Hiroyuki Harada, Hidetaka Kawakita, et al. Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid. Int J Mater Sci Appl. 2017;6(4):212-222. doi: 10.11648/j.ijmsa.20170604.18

    Copy | Download

  • @article{10.11648/j.ijmsa.20170604.18,
      author = {Hari Paudyal and Bimala Pangeni and Katsutoshi Inoue and Hiroyuki Harada and Hidetaka Kawakita and Keisuke Ohto and Shafiq Alam},
      title = {Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid},
      journal = {International Journal of Materials Science and Applications},
      volume = {6},
      number = {4},
      pages = {212-222},
      doi = {10.11648/j.ijmsa.20170604.18},
      url = {https://doi.org/10.11648/j.ijmsa.20170604.18},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijmsa.20170604.18},
      abstract = {Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.},
     year = {2017}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Adsorptive Removal of Trace Concentration of Fluoride Using Orange Waste Treated Using Concentrated Sulfuric Acid
    AU  - Hari Paudyal
    AU  - Bimala Pangeni
    AU  - Katsutoshi Inoue
    AU  - Hiroyuki Harada
    AU  - Hidetaka Kawakita
    AU  - Keisuke Ohto
    AU  - Shafiq Alam
    Y1  - 2017/07/24
    PY  - 2017
    N1  - https://doi.org/10.11648/j.ijmsa.20170604.18
    DO  - 10.11648/j.ijmsa.20170604.18
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 212
    EP  - 222
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20170604.18
    AB  - Novel adsorption gel was prepared from orange juice residue by using boiling concentrated sulfuric acid to create a condensation cross-linking reaction. It was then loaded with Zr(IV) ion to create adsorption sites for fluoride ions. This prepared gel was characterized by IR, EDX, XRD, SEM and chemical analysis. Fluoride adsorption was strongly pH dependent and maximum adsorption occurred at pH 3-4. The maximum adsorption capacity was drastically improved by loading Zr(IV) from 0.21 mmol/g up to 0.71mmol/g at 303 K. The thermodynamic parameters evaluated from adsorption isotherms at varying temperature suggested that adsorption of fluoride onto the present adsorbent is spontaneous and endothermic in nature. The adsorbed fluoride was successfully desorbed using dilute alkaline solution. Trace concentrations of fluoride contained in the actual waste plating solution was completely removed by adding small amounts of this adsorbent.
    VL  - 6
    IS  - 4
    ER  - 

    Copy | Download

Author Information
  • Department of Applied Chemistry, Saga University, Saga, Japan

  • Department of Applied Chemistry, Saga University, Saga, Japan

  • Department of Applied Chemistry, Saga University, Saga, Japan

  • Department of Environmental Sciences, Prefectural University of Hiroshima, Hiroshima, Japan

  • Department of Applied Chemistry, Saga University, Saga, Japan

  • Department of Applied Chemistry, Saga University, Saga, Japan

  • Department of Science, Memorial University, St. John’s, NL, Canada

  • Sections